Polyhydroxybutyrate

    • Product Name: Polyhydroxybutyrate
    • Chemical Name (IUPAC): poly(3-hydroxybutanoic acid)
    • CAS No.: 26063-37-8
    • Chemical Formula: (C4H6O2)n
    • Form/Physical State: Solid
    • Factroy Site: No.1 Hengli Road Economic Development Zone of Nanma ShengzeTown,Wujiang District
    • Price Inquiry: sales3@ascent-chem.com
    • Manufacturer: Hengli Petrochemical Co., Ltd.
    • CONTACT NOW
    Specifications

    HS Code

    405849

    Chemical Name Polyhydroxybutyrate
    Abbreviation PHB
    Chemical Formula (C4H6O2)n
    Molecular Weight Approximately 86 g/mol (monomer unit)
    Appearance White, brittle, thermoplastic polyester
    Density 1.25 g/cm³
    Melting Point 175 °C
    Glass Transition Temperature Around 5 °C
    Biodegradability Biodegradable
    Solubility Insoluble in water, soluble in chloroform
    Production Method Microbial fermentation
    Tensile Strength 40 MPa
    Relative Crystallinity 60–80%
    Thermal Decomposition Temperature Around 290 °C

    As an accredited Polyhydroxybutyrate factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Application of Polyhydroxybutyrate

    Purity 99%: Polyhydroxybutyrate with purity 99% is used in biomedical sutures, where biocompatibility and controlled degradation are achieved.

    Molecular Weight 500 kDa: Polyhydroxybutyrate with molecular weight 500 kDa is used in packaging films, where high mechanical strength and flexibility are provided.

    Melting Point 175°C: Polyhydroxybutyrate with melting point 175°C is used in injection molding applications, where thermal stability during processing is ensured.

    Particle Size 10 µm: Polyhydroxybutyrate with particle size 10 µm is used in 3D printing filaments, where uniform extrusion and surface smoothness are realized.

    Viscosity Grade 800 cP: Polyhydroxybutyrate with viscosity grade 800 cP is used in biodegradable coatings, where optimal flow and film formation are achieved.

    Stability Temperature 140°C: Polyhydroxybutyrate with stability temperature 140°C is used in hot beverage cup liners, where product shape retention under elevated temperature is maintained.

    Residual Monomer ≤0.5%: Polyhydroxybutyrate with residual monomer ≤0.5% is used in food contact materials, where safety and low extractables are ensured.

    Glass Transition Temperature 5°C: Polyhydroxybutyrate with glass transition temperature 5°C is used in agricultural mulch films, where flexibility at low ambient temperatures is provided.

    Water Absorption Rate 0.2%: Polyhydroxybutyrate with water absorption rate 0.2% is used in electronic device casings, where dimensional stability in humid environments is maintained.

    Crystallinity 60%: Polyhydroxybutyrate with crystallinity 60% is used in disposable cutlery, where rigidity and snap resistance are enhanced.

    Packing & Storage
    Packing White, resealable polyethylene bag labeled "Polyhydroxybutyrate (PHB)", 500 grams, includes safety pictograms and batch number for traceability.
    Container Loading (20′ FCL) Container Loading (20′ FCL) for Polyhydroxybutyrate: 10-12 metric tons packed in 25kg bags, shipped on pallets for secure transport.
    Shipping Polyhydroxybutyrate (PHB) is shipped as a biodegradable polymer in solid pellet or powder form, typically packed in moisture-resistant, sealed containers or bags. Shipping requires protection from heat, sunlight, and moisture to prevent degradation. Standard transport applies as it is generally non-hazardous, but local regulations should be reviewed prior to shipment.
    Storage Polyhydroxybutyrate (PHB) should be stored in a cool, dry, and well-ventilated area, away from direct sunlight and sources of heat. It must be kept in tightly closed containers to prevent moisture absorption and contamination. Avoid contact with strong acids, bases, and oxidizing agents. Proper storage maintains its biodegradability and prevents degradation or changes in its physical and chemical properties.
    Shelf Life Polyhydroxybutyrate typically has a shelf life of 1–2 years when stored in cool, dry conditions away from direct sunlight.
    Free Quote

    Competitive Polyhydroxybutyrate prices that fit your budget—flexible terms and customized quotes for every order.

    For samples, pricing, or more information, please contact us at +8615365186327 or mail to sales3@ascent-chem.com.

    We will respond to you as soon as possible.

    Tel: +8615365186327

    Email: sales3@ascent-chem.com

    Get Free Quote of Hengli Petrochemical Co., Ltd.

    Flexible payment, competitive price, premium service - Inquire now!

    More Introduction

    Polyhydroxybutyrate (PHB): New Solutions for Sustainable Manufacturing

    Our Experience with Polyhydroxybutyrate

    Understanding today’s plastics market means recognizing a shift that has everyone talking: sustainability is no longer just a buzzword, it’s the direction we see our industry heading. Polyhydroxybutyrate, or PHB, stands out as one of the few biopolymers that holds real promise for changing how the world thinks about plastic. Years of developing, testing, and refining PHB on our own production floors have given us valuable experience not only in delivering a technically advanced material, but in seeing how PHB actually stands up under day-to-day industrial use. As a direct manufacturer, we’re not simply moving finished goods from warehouse to warehouse; we’re involved in every step that brings PHB from raw fermentation to the final pellet.

    PHB Production: Bioprocessing at Its Core

    The process starts in our fermentation tanks, where specific strains of bacteria feed on sugars. They naturally produce PHB as a reserve material, similar to how plants store starch. Over years of research, it’s become clear that fine-tuning the fermentation process determines not just efficiency, but also some of the core physical characteristics of the resin. Optimizing nutrient inputs and maintaining stable cultures leads to more consistent molecular weights and fewer off-spec batches.

    Compared to petroleum-based plastics, the process avoids high temperatures and toxic chemicals. The downstream extraction and purification have their own challenges — PHB granules are delicate until they’re properly processed and stabilized. Our units capture and reuse side stream materials and solvents, both reducing waste and keeping our operational costs in check. This experience has taught us to respect the balance between scaling up for larger production runs and protecting the quality of every batch that ships to our clients.

    Physical Properties and Performance in Manufacturing

    PHB is a member of the polyhydroxyalkanoate family, but what sets it apart is its close match to some common polyolefins on the market. Stiffness and tensile strength put it next to polypropylene, and our extrusion lines have proven that converting existing film, thermoforming, or injection molding processes to run PHB only takes small tweaks in set points. Melt flow rates typically fall in the range familiar to most processors — our standard PHB grades deliver melt flow indices spanning from lower numbers suitable for sheet extrusion up to higher ranges that perform well in fiber spinning.

    We’ve measured mechanical performance under real-world conditions: impact resistance, elongation at break, and barrier properties. PHB stands out in applications needing clarity and gloss, like packaging films, though it does have some brittleness if not plasticized or blended correctly. It handles heat at levels up to about 170° Celsius before softening, so hot-fill compatibility in food and beverage packaging comes within reach. In electrical applications, results from our test labs show PHB’s dielectric properties sit near those of traditional plastics, offering insulation in lower-voltage components.

    Comparing PHB to Conventional Plastics

    Across our workbench, the conversation often centers around material substitution. Companies ask us: does PHB really work as a “drop-in” alternative? In common commodity applications, it often does. Polyethylene and polypropylene both set a high bar for simplicity and cost, but PHB’s performance curve gets within range in arrays of products like single-use trays, containers, and bottles.

    Where PHB carves out a strong reputation is in its ability to fully biodegrade under industrial composting conditions. Extensive field trials show we regularly see complete breakdown in less than six months at 58°C and humidity above 80%, certified by European and US compostability standards, without leaving behind microplastics or persistent residues. Polyethylene and polypropylene remain unchanged after years, requiring landfill or mechanical recycling. PET, popular in bottles and food containers, stands up well mechanically but lags behind PHB’s bio-based and biodegradable credentials.

    A second point: PHB’s oxygen and water vapor barrier surpasses most biodegradable bioplastics, making it significantly more suited for shelf-life extension in perishable packaging. PLA gets close for some food wraps, but the water sensitivity of PLA means PHB outperforms it in more humid environments such as fresh produce packs.

    Tackling Challenges Head-On

    Every new material has hurdles. Sourcing high-quality feedstocks remains a resource-intensive process. We deal directly with regional agriculture co-operatives to ensure the glucose or sucrose reaching our tanks meets the required purity for trouble-free fermentation. Waste sugars or byproducts from other sectors occasionally tempt the cost-conscious, but they risk introducing contaminants that both lower yield and threaten downstream performance.

    PHB has lower thermal stability than some fossil-based plastics. It’s prone to thermal degradation at temperatures closer to its melting point, releasing small amounts of butyric acid. To counteract this, we focus on tight process control on our extruders and injection molders to rapidly melt and shape the resin, with as little hold time at max temperature as possible. In our facilities, we maintain precise temperature profiles and make regular quality checks for color, odor, and flow. Customers new to PHB sometimes experience yellowing or ‘off’ smells until processing conditions are tuned. Our technical support staff frequently visit client plants to walk engineering teams through these changes, ensuring clean transitions and smoother production runs.

    Economic competitiveness presents a separate challenge. PHB’s reliance on fermentation and feedstock inputs makes it more costly than mass-market resins. As the fermentation route becomes more energy- and water-efficient, and with scale-up reducing manufacturing margins, costs continue to fall — last year we saw production costs drop by nearly 18% compared to five years ago. Innovative partnerships with specialty end-users, niche packaging, and healthcare segments have allowed us to keep volumes high without overwhelming market demand.

    Environmental Benefits and Real-World Applications

    We have seen a steady increase in requests from brands and converters seeking not just to claim “bio-based” on packaging, but to provide data-backed environmental benefits. Our PHB comes with full lifecycle analysis covering emissions, land use, and water impact from corn or sugarcane fields to finished resins. Average fossil energy savings run 25% to 30% lower than oil-based plastics. As circular economy targets stiffen, composters and municipal waste sites have confirmed our PHB grades disappear in controlled settings, supporting city and state zero-plastic-waste initiatives.

    In everyday production, PHB finds a home in rigid containers, transparent trays, single-use cutlery, agricultural mulch films, and even medical-grade items such as surgical drapes and wound dressings. One client uses our PHB for oyster packaging, capitalizing on both shelf-life and rapid composting after use. Specialty blends with other polyhydroxyalkanoates give more flexibility, offering toughness suited for automotive clips and casings — places where “biodegradable” used to be synonymous with “fragile.”

    We routinely supply converters using standard extrusion, blow molding, injection molding, and fiber-spinning equipment. Molders tell us the cycle times for PHB closely mirror polyolefins. Processors looking for thin, breathable films will notice PHB’s ease with orientation and stable gauge, letting them dial in precisely the properties needed for fresh-food wraps or medical barriers. For 3D printing, our R&D team recently fine-tuned PHB filament grades, reporting layer adhesion and print accuracy that surpasses entry-level bioplastics.

    PHB in Context: Sustainable Material Choice

    Sustainability claims draw scrutiny, and many customers seek independently verified certifications. We work directly with global certifiers for compostability (EN 13432, ASTM D6400), food contact safety, and biobased content. Audit-ready traceability backs up every lot leaving our plant. As regulations shift — whether single-use bans in Europe or plastic taxes in Asia — being able to guarantee product compliance positions our customers ahead of new rules, rather than scrambling to catch up.

    Waste management benefits go beyond composting: several regions have trialed PHB materials in home composting and soil-biodegradation, both of which deliver measurable breakdown within a year, depending on climate and conditions. Field tests in agriculture show PHB mulching films plowed under at harvest didn’t linger, and no adverse soil effects were observed. For communities pushing for landfill diversion and agricultural waste solutions, PHB supplies a genuine step forward.

    Healthcare and food packaging users weigh contamination risks closely. Our cleanroom-grade PHB passes the thresholds for sterility and extractables, all produced in facilities following strict GMP protocols. PHB’s lack of toxic additives further reduces regulatory hurdles for sensitive markets.

    Design Considerations: Lessons from Our Clients

    Customers sometimes arrive expecting one-to-one swap-outs for old polyolefins. The biggest lessons come on the production line. PHB allows similar throughput and equipment settings, but its processing window is narrower, requiring careful calibration during startup. If a molding line runs too hot, PHB flashes and loses gloss; too cold, it brings voids and surface defects. In films, attention to take-up speed and cooling delivers crisp, bubble-free reels.

    Another consideration: shelf-life stability versus environment-driven breakdown. Because PHB is biodegradable, it begins to lose structural integrity in composting or humid conditions after its service life. Careful formulation using stabilizers extends shelf storage without sacrificing compost performance after use. For applications needing higher impact or toughness, we recommend PHB blends, such as with polyhydroxyvalerate (PHV), to realign mechanical properties while keeping the end-of-life benefit.

    Printing and decoration on PHB surfaces, including inks and adhesive labels, stick well after minor pre-treatments. Our print shop partners report trouble-free runs compared to recyclable olefins. High transparency makes PHB attractive in point-of-sale packaging that must both protect and showcase premium products.

    Innovating Beyond Commodity: What the Future Holds

    As we scale capacity and grow our team’s expertise, questions about next-generation PHB grades keep us moving. Polymer blending, melt rheology adjustments, and advancing fermentation strains top the R&D agenda. New co-polymer approaches target both softness and elongation, climbing closer to flexible polyethylene’s benchmark but without long-term persistence in the environment.

    We’re also pursuing route-to-market collaborations that make the most sense nearby our production base: integrating PHB compounds into locally made goods, cutting down on transport, and offsetting emissions. Cross-sector pilots in agriculture, food service, and medical packaging provide test beds to validate new formulations. Local investment accelerates feedback, ensuring that every adjustment in manufacturing supports customer needs rather than speculative trends.

    Lately, supply chain transparency has become just as vital as raw capacity. Our team continues to digitize records and trace product movement from field to factory, building customer trust and confidence as environmental claims undergo heavier inspection.

    Next Steps: Building Meaningful Change Through PHB

    Polyhydroxybutyrate production hasn’t always moved at the pace planners hoped for fifteen years ago. The lessons we’ve learned — both from smooth launches and from the tough moments — show us where PHB provides its greatest value: it offers brands a way to shift environmental footprint, meets real technical needs, and opens doors to innovation in product design.

    Regulators, brands, and consumers all pull plastics in different directions. From inside our manufacturing floors, the best approach to PHB isn’t hype or unsubstantiated claims — it’s in making sure the resin our lines produce can deliver on every promise, from composting to strength to visual appeal. Our ongoing investment in improved fermentation technology, downstream processing innovation, and close partnerships with our supply base ensures that as the market matures, both workable and scalable solutions stay available to everyone seeking true sustainability.