1,4-Butanediol

    • Product Name: 1,4-Butanediol
    • Chemical Name (IUPAC): Butane-1,4-diol
    • CAS No.: 110-63-4
    • Chemical Formula: C4H10O2
    • Form/Physical State: Liquid
    • Factroy Site: No.1 Hengli Road Economic Development Zone of Nanma ShengzeTown,Wujiang District
    • Price Inquiry: sales3@ascent-petrochem.com
    • Manufacturer: Hengli Petrochemical Co., Ltd.
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    Specifications

    HS Code

    452772

    Chemical Name 1,4-Butanediol
    Synonyms BDO, Tetramethylene glycol
    Cas Number 110-63-4
    Molecular Formula C4H10O2
    Molecular Weight 90.12 g/mol
    Appearance Colorless, oily liquid
    Odor Odorless
    Melting Point 20.1 °C
    Boiling Point 230 °C
    Density 1.017 g/cm³ at 20 °C
    Solubility In Water Miscible
    Flash Point 121 °C (closed cup)
    Vapor Pressure 0.01 mmHg at 20 °C

    As an accredited 1,4-Butanediol factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Application of 1,4-Butanediol

    Purity 99.5%: 1,4-Butanediol with purity 99.5% is used in spandex fiber production, where it ensures high molecular weight polymer formation for superior elastic recovery.

    Viscosity grade 300 mPa·s: 1,4-Butanediol of viscosity grade 300 mPa·s is used in polyurethane systems, where it contributes to controlled processing and uniform cell structure.

    Molecular weight 90.12 g/mol: 1,4-Butanediol with molecular weight 90.12 g/mol is used in polyester resin synthesis, where it guarantees consistent chain extension and enhanced mechanical strength.

    Melting point 20.1°C: 1,4-Butanediol with a melting point of 20.1°C is used in solvent applications, where it provides stable liquid handling at room temperature.

    Water content ≤0.05%: 1,4-Butanediol with water content ≤0.05% is used in pharmaceutical intermediates, where it enables high yield and product purity in downstream processing.

    Stability temperature up to 70°C: 1,4-Butanediol stable up to 70°C is used in adhesive formulations, where it maintains viscosity and prevents premature polymerization during application.

    Color (APHA) ≤10: 1,4-Butanediol with color (APHA) ≤10 is used in high-grade coatings, where it ensures clarity and optimal aesthetic performance.

    Acid value ≤0.05 mg KOH/g: 1,4-Butanediol with acid value ≤0.05 mg KOH/g is used in rigid foam manufacturing, where it minimizes side reactions and maximizes foam integrity.

    Density 1.017 g/cm³: 1,4-Butanediol with a density of 1.017 g/cm³ is used in automotive plastics compounding, where it enables precise blending and reliable end-product consistency.

    Storage temperature 5–35°C: 1,4-Butanediol stored at 5–35°C is used in industrial process lines, where it retains chemical stability and prevents decomposition.

    Packing & Storage
    Packing 1,4-Butanediol is packaged in a 25-liter blue HDPE drum with a tight-sealed cap and clear hazard labeling.
    Container Loading (20′ FCL) 1,4-Butanediol is shipped as a liquid in 20′ FCL ISO tanks or drums, ensuring safe, efficient bulk transportation.
    Shipping **Shipping for 1,4-Butanediol:** Transport 1,4-Butanediol in tightly sealed, properly labeled containers, protected from moisture and sources of ignition. Ship according to local, national, and international regulations for handling chemicals. Ensure compatibility with packaging materials and provide safety documentation, including Material Safety Data Sheets (MSDS), during shipment to guarantee safe and compliant transport.
    Storage 1,4-Butanediol should be stored in tightly closed containers, away from heat, sparks, and open flames, in a cool, dry, well-ventilated area. Protect it from moisture and direct sunlight. Keep separate from strong acids, oxidizers, and bases. Use containers made of compatible materials, such as stainless steel or certain plastics, to prevent reactions and maintain chemical stability.
    Shelf Life 1,4-Butanediol typically has a shelf life of 2 years when stored tightly sealed in a cool, dry, well-ventilated area.
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    More Introduction

    1,4-Butanediol: Direct from the Manufacturer

    Our History with 1,4-Butanediol

    We have been producing 1,4-Butanediol for decades, following improvements in catalytic hydrogenation processes, and staying close to the pulse of industrial demands. Each lot rolling off our line reflects adjustments based on what global manufacturers in resins, fibers, and solvents request, and what we see in testing protocols across industries. Over time, we streamlined our setup to deliver high-purity 1,4-Butanediol—a colorless, thick liquid with a faint sweet scent—packaged and shipped straight from our plant. Input from users in synthesis labs, polymerization projects, and R&D has shaped not just how we refine the product, but the support and transparency we provide with every shipment.

    What Does 1,4-Butanediol Offer?

    1,4-Butanediol (BDO) shows up in a surprising number of industrial products. Our material—CAS number 110-63-4—heads mostly into making polybutylene terephthalate (PBT) resins, THF (tetrahydrofuran), and GBL (gamma-butyrolactone). Each of these brings different markets: engineering plastics, spandex fabric, and high-performance solvents. We keep impurities under 0.1%, with water content lower than 0.05%, meeting needs both of large polymer plants and small specialty chemical shops. Phthalate testing and trace metal analysis tools in our quality labs examine every batch, because downstream synthetic reactions sometimes stall on trace contaminants.

    On the plant floor, 1,4-Butanediol shows its flexibility. It reacts with diacid components to form polyesters, delivers elasticity for spandex filament, adds connectivity as a chain extender in polyurethanes, and acts as a key building block for THF production via dehydration. Each synthesis turns out differently depending on trace moisture, sample age, and mineral content—which we routinely monitor, because these small details weigh heavy in large manufacturing runs.

    Specifications That Make a Difference

    From experience, consistency is everything. We standardize our main grade at a purity above 99.7%, matching international benchmarks, with options for ultra-high-purity requests in pharmaceutical and electronic applications. This matters, because in thermal polymerizations and catalytic hydrogenation steps, logged impurity levels can quickly translate to sticky process lines or inconsistent end product color.

    Users often talk about viscosity, so we record values at 25°C; our BDO holds steady at roughly 80-90 mPa·s. The density sits around 1.017 g/cm3, and it stays liquid above 20.1°C, meaning bulk shipments rarely face crystallization in moderate climates. There’s no lingering solvent smell, as confirmed by both batch certificates and years of customer feedback from manufacturers using BDO as a co-monomer.

    Direct Experience on the Production Line

    Working up close with BDO, we see where tiny variances in feedstock or process pressure show up later in thermal stability and reactivity. Polyesters made from BDO need tight glycol controls, otherwise the polymer chains grow uneven or yellow on extrusion. Polyurethane plants look for minimal aldehydes, recognizing that even a few ppm can affect foam formation at scale. Packaging started in steel drums, but bulk ISO tanks now fill most orders, with corrosion-resistant linings—there’s no shortcut to protecting this product from air and light. We built sampling routines into loading areas, not only to check for basic purity, but to measure possible contamination from pumps or valves.

    Technical support means more than sending a certificate. When a customer’s batch reacts differently, our lab pulls retention samples, runs Karl Fischer titration, cross-checks GC-MS data, and, if needed, provides a complete breakdown of trace organic and inorganic content. This approach grew out of years of feedback, sometimes coming from makers of specialty adhesives, sometimes from large-scale fiber manufacturers overseas.

    Uses and End Products Informed by Field Experience

    In the real world, BDO doesn’t only end up as fiber or plastic. Solvent and reagent streams in electronics, specialty coatings, and biodegradable polyesters trace back to our site. Large THF producers rely on steady BDO deliveries: dehydration reactions call for water levels beneath 300 ppm, or their yields fall off. Polyurethane plants using BDO as a chain extender balance pure input streams to get reliable flexibility; BDO’s clean glycol structure delivers softer, more resilient foams without unwanted plasticizer leaching. In resin and surface coating work, 1,4-Butanediol adds controlled reactivity, giving chemists more latitude to tweak mechanical properties without sacrificing safety.

    Occasionally, we field requests from pharmaceutical clients. While BDO has limited direct applications in active pharmaceutical ingredients, it shows up in specialty solvents and as a reagent in select synthesis routes. Here, residual by-products, halide content, and even packaging cleanliness level come under closer scrutiny. BDO destined for fine chemicals meets a stricter impurity profile, with tailored logistics and batch-level documentation.

    What Sets It Apart from Other Glycols

    Production and application teach sharp lessons on differences between BDO and other glycols—like ethylene glycol, propylene glycol, or even 1,2-butanediol. BDO carries two terminal hydroxyl groups four carbons apart, giving its reaction profile more length and flexibility. Compared to ethylene glycol, BDO forms polymers with greater toughness and hydrolytic stability. It avoids the sweetness and higher volatility of ethylene glycol, making it better suited for high-temperature engineering plastics. Polyurethanes built with BDO stand up longer against moisture and mechanical wear.

    1,2-Butanediol shows higher water solubility and different reactivity. Its secondary alcohol structure reacts differently in esterification and polymerization, producing softer plastics or less durable coatings. BDO stands out by balancing a low freezing point with low toxicity, lessening risk during shipping and handling. In making spandex, no direct substitute matches BDO’s chain-extending properties, and most process engineers recognize the sharp difference in final stretch and strength.

    Propylene glycol competes more in food and personal care. Although it’s safer for ingestion, it can’t match BDO in producing high-molecular-weight polymers. In industrial use, switching to ethylene or propylene glycol usually signals a shift to lower-cost or lower-performance finished goods. We often advise design engineers and formulators which glycol suits their functional and regulatory needs: most firms sticking with BDO do so for a proven track record in durability, solubility, and processing flexibility.

    Challenges in Manufacturing and Market Supply

    Tightening supply chains and regulatory shifts affect daily operations. Dehydrogenation catalysts and feedstock purities carry long lead times. BDO production lives or dies on the quality of maleic anhydride or acetylene supply, which both see volatility driven by global petrochemical trends. Power outages or minor contamination shut lines down quickly, and years of troubleshooting teach us to isolate and fix root problems before restarting production.

    Environmental emissions matter, so all our waste handling passes a third-party audit, with spent catalysts and reaction by-products tracked from source to disposal. Regulators in Europe and North America pay close attention to VOC (volatile organic compound) output and workplace exposure limits. We monitor every emission and keep a log for each load, knowing that trace VOCs result from minor leaks or maintenance lapses. This isn’t about ticking boxes but about building trust with downstream partners who can’t risk regulatory shutdowns or unexpected emissions.

    To manage demand spikes, we maintain a rolling inventory and work directly with logistics partners. Insulation and minimal dead space in rail and tank containers prevent crystallization during winter. Years back, one rough winter taught us to pre-warm tanks and create detailed temperature tracking—costly mistakes drive home how physical handling affects product quality from dock to destination.

    Quality as a Continuous Discipline

    No two lots are identical without strict oversight. Routine sampling at every step, from raw material intake to finished product storage, keeps us ahead. We validate our analytical instruments and run round-robin tests with partner labs to ensure accuracy in moisture, aldehyde, and acid content readings.

    Failures in production almost always track back to lapses in equipment hygiene, uncalibrated instruments, or logistic bottlenecks. We invest heavily in automatic filtration, clean-in-place systems for pipelines, and operator training. Technical support never cuts corners; if a problem shows up on a customer line, we replicate their process in our pilot lab—debugging isn’t a phone call, but an ongoing collaboration.

    BDO’s stability comes into question when stored too long without temperature control. In hot climates or under direct sunlight, slow oxidation can create yellowing or off-odors. We remind customers—especially those in subtropical regions—that temperature logs serve as insurance against unexplained quality shifts. Our logistics crew is well-versed in scraping, tank cleaning, and regular lid inspections, which together prevent costly off-spec shipments.

    Safety and Sustainability Focused on Practice

    BDO’s moderate toxicity means careful handling, but safe long-term storage doesn’t require elaborate ventilation under normal conditions. Spills present low fire risk but still need local exhaust and prompt cleanup. Our plant’s spill kits and sealed transfer lines draw on years of incident reviews—simple protocols, but critical for keeping operators healthy and operations uninterrupted. We supply training for new clients by invitation, based on actual lessons from our own teams.

    Environmental monitoring and responsible chemical handling aren’t only about passing inspections. We design every process step to recover waste, recycle solvents, and minimize water discharge. Scrubbers, closed drainage circuits, and catalyst recycling save money and reduce local impact. Local community engagement comes from open-door events and published audit reports. Over time, more buyers care about how their raw material choices affect downstream carbon footprints—BDO’s durable end products often mean less frequent replacement, a point we highlight in discussions with sustainable design teams.

    Innovation through Customer Collaboration

    Most improvements in BDO quality come from collaborating with process engineers, resin compounders, and R&D specialists who encounter the real problems. A specialty fibers plant in East Asia once returned half a load because of trace contamination. Root cause: a rarely-used connector hose contained a non-standard material. Fixing the process involved not only swapping out equipment, but retraining staff and creating a digital checklist for every loading operation. This level of communication turns customer complaints into future quality gains.

    The range of possible applications keeps growing. New work in biodegradable packaging often circles back to BDO’s unique position in producing flexible but strong polymers that decompose under controlled composting. Rigid, high-gloss automotive plastics increasingly use BDO-based resins instead of purely aromatic types, targeting weight reduction and energy savings. Each customer brings a new set of expectations, safety needs, and technical questions—our greatest asset is a team ready to troubleshoot, document, and adapt.

    BDO’s versatility attracts both innovation and scrutiny. Keeping ahead means more than keeping certifications up to date—it means preempting shifts in global regulation, following REACH and GHS chemical safety guidelines, and keeping clients supplied with reference samples for their audits. We believe future demand will come from medical device substrates, high-performance adhesives, and next-generation compostable plastics, while legacy uses in fibers and solvents will remain steady.

    Looking to the Future: Adapting for Tomorrow's Challenges

    Thinking forward, we pay close attention to shifts in renewable feedstocks. Most BDO today traces its carbon back to oil and gas, but pilot plants show promise with fermentative and bio-based routes. These show slightly higher end-product price, but lower environmental impact. Industrial adoption will depend on matching the purity and processability needed by established users—experience reminds us of the long timelines and iterative tests involved. Our pilot projects in green BDO follow the same rigorous certification and validation process as our main product line.

    Clients ask about life cycle analysis, carbon emissions, and supply risk. We supply detailed, transparent data on each batch, and welcome independent audits. Users in regulated markets rely on full documentation not just for compliance, but for certification in markets where “green chemistry” earns a competitive edge. Drawing on hands-on production history, we recognize this shift as both a challenge and an opportunity—our expertise isn’t theoretical, it’s earned through measurable outcomes and practical solutions.

    Why Source Directly From Us

    Years in manufacturing teach that every ton of BDO represents more than a transaction. Control over inputs, process settings, packaging, and technical support gives users confidence in their end products. We work alongside compounders, production managers, and R&D teams to give more than just a spec sheet. Whether you’re scaling up a biodegradable resin line or refining a polyurethanes formula, direct sourcing ensures traceability, accountability, and collaboration that no broker or trader can match.

    Our commitment remains to technical excellence, long-term relationship building, and continuous process improvement. Customer feedback shapes how we produce, pack, and deliver every delivery. In a changing global market, this focus on direct partnership and shared problem-solving will continue to anchor our approach. For anyone evaluating glycols or advanced intermediates, experience counts, and we bring ours to work every day, straight from our plant to your process.